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it's a curve, not a straight line). The rate increases because the enzyme and substrate molecules both have more kinetic energy so collide more often, and also because more molecules have sufficient energy to overcome the (greatly reduced) activation energy. The increase in rate with temperature can be quantified as a Q10, which is the relative increase for a 10°C rise in temperature. Q10 is usually 2-3 for enzyme-catalysed reactions (i.e. the rate doubles every 10°C) and usually less than 2 for non-enzyme reactions.
The rate is not zero at 0°C, so enzymes still work in the fridge (and food still goes off), but they work slowly...
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