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This temperature is a true measure of the forces of attractions between molecules as molecules separate from one another when they turn from a liquid to a gas.
The stronger the attractions between particles (molecules or ions), the more difficult it will be to separate the particles. When substances melt, the particles are still close to one another but the forces of attraction that held the particles rigidly together in the solid state have been sufficiently overcome to allow the particles to move. When substances boil, the particles are completely separated from one another and the attractions between molecules are completely overcome...
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