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When lime is mixed with the water in ethanol, calcium hydroxide forms. The calcium hydroxide can then be separated from the ethanol. Similarly, a hygroscopic material will dissolve some of the water content of the ethanol as it passes through, leaving a purer alcohol.[1]
[edit] Addition of an entrainer
The ethanol-water azeotrope can be broken by the addition of a small quantity of benzene or cyclohexane. Benzene, ethanol, and water form a ternary azeotrope with a boiling point of 64.9 °C. Since this azeotrope is more volatile than the ethanol-water azeotrope, it can be fractionally distilled out of the ethanol-water mixture, extracting essentially all of the water in the process...
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