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Ozone is produced from relatively longer-wavelength solar radiation under NOx and non-methane hydrocarbons rich environments. These photochemical reactions possibly bring about photochemical smog in urban area.
http://www.asahi-net.or.jp/~wt2y-ttm/what.htm
The characteristics of the tropospheric ozone
About 8 % of the total column ozone is in the troposphere. The tropospheric ozone also plays an important role in the atmosphere.
1) Ozone is a green house gas and possibly contributes to the global warming.
2) Ozone is harmful for human being and crops in the troposphere.
3) Ozone oxidizes many chemical substances in the troposphere, and controls tropospheric chemistry...
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