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In the addition polymerisation of natural rubber, the two double bonds in isoprene open up to form a polymer that contains only one double bond (2). One problem with natural rubber, which prevents it from being used on its own in tyres, is its thermoplastic nature. This problem can be solved by curing the rubber by heating it with sulphur, described later as vulcanisation.
It is impossible to recreate exact conditions for natural rubber synthesis in the laboratory. So when synthetic rubber was first produced, by the polymerisation of dienes, the products were of a poor quality. A better quality rubber was obtained by the polymerisation of butadiene to form poly(butadiene)...
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