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This is said because chlorophyll absorbs red and blue wavelengths of light and reflects green wavelengths of light. When referring to the light spectrum, red and violet are furthest away from green, and would be most absorbed by the leaf. White light is all the colors of the spectrum, and would have results similar to that of red and blue.
Below is a chart provided by Daniel Winik of Sidwell Friends School in Washington, DC. A similar experiment was done using Arabidopsis thaliana plants. The purpose of his experiment was Oto observe the effects of different wavelengths of light on the rate of photosynthetic rate in Arabidopsis thaliana plants...
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