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This is because electrons cannot get enough energy to overcome their atomic bonding. The photoelectric effect furthered wave particle duality, whereby physical systems (i.e.: photons in this case) can display both wave - like and particle ? like properties and behaviours, a concept used by the creators of quantum mechanics. It was explained mathematically by Einstein, utilising work in quantum mechanics, and was developed by people like Max Planck.
The photoelectric effect was not just an immediate discovery with a definite drawn conclusion. It involved many years of research, experimentation and debating...
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