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The 1,3-diene must be in a conformation that allows the formation of a new six-membered ring. This conformation is called the s-cis conformation. The s stands for sigma or single bond, and the two ? bonds are on the same side of the single bond. Hence, the conformation is s-cis, meaning the two ? bonds are cis with respect to the single bond. The other conformation that allows the ? system to be planar is called the s-trans conformation. A new six-membered ring cannot form from the s-trans conformation of the diene.
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Thus, one reactant is a 1,3-diene that can adopt an s-cis conformation...
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