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The larger elements such as Bromine and Iodine are larger molecules with a larger amount of intermolecular force between each electron. This increase in intermolecular attraction means that the required heat energy to reach the boiling point increases. Fluorine has a significantly lower boiling point than the rest of the halides because it has a set of electrons that produces repulsion between them. This weakens the bond. Chlorine has a boiling point of -34.6°C because its covalent bond is stronger than fluorine’s and so on until Iodine which has a boiling point of 184.0°C because it has many more energy levels which requires more heat energy...
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