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The thickest an airspace should be is 1 inch because any thicker than that will cause the glass of the window to no longer insulate the building.
The air in between the layers of glass should be thick and dense, so that it can save energy. One of the most common airs used in-between glass is argon. When argon is used heat loss is reduced. You could also use carbon dioxide or sulfur hexa-fluoride between glass.
Another type of window that is used commonly to keep the home cool is tinted glass. Tinted glass and tinted window films are used on buildings to reduce heat gain through windows. Advancements in tinted glass have now allowed us to make the glass appear just as a regular window that you can see through...
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