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The more complex the substituent, the reaction will go at lower temperatures and under milder conditions. The one rule the diene does have to follow is that it has to be is cis-conformation. This is because the trans-conformation of the same diene would be non-reactive because it is so stable. The dieneophile in a typical Diels-Alder reaction would contain a phenyl group or some sort of electron-withdrawing group. This electron-withdrawing group is what will help in bonding the diene and the dienophile together. The Diels-Alder reaction is widely used in organic chemistry because it requires little energy...
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