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Essay text:
Although these categories
are not mutually exclusive, it is not uncommon to find compounds that
exhibit only one or the other of the two types. Most geometrical
isomers result from cyclic systems or restricted rotation about double
bonds. The preparation of fumaric acid by isomerization of maleic acid
and addition of molecular bromine to fumaric acid was illustrated in
the experiment.
Geometric isomers can be interconverted if the double bond is
temporarily converted to a single bond, about which rotation is
relatively free. For example, an electrophile adds to the double bond,
rotation becomes possible...
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