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The oxygen radicals react with nitrogen forming nitrogen monoxide which is further oxidised to form nitrogen dioxide. NOx is also formed in nitrogen compounds such as impurities in fuel.
In light NOx reacts with hydrocarbons producing photochemical oxidants which are harmful substances, these include peroxyacetyl nitrate or PAN and ozone (Article 1, Paved with titanium). See skeletal formula right (http://upload.wikimedia.org/wikipedia/commons/thumb/1/1d/Peroxyacetyl-nitrate-2D-skeletal.png/800px-Peroxyacetyl-nitrate-2D-skeletal.png) The photochemical reaction between NOx and oxygen forms ozone as its concentration increases...
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