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Essay Details:
Essay text:
The
synthesized Jacobsen's catalyst was used to catalyze the epoxidation of
dihydronaphthalene. The products of this reaction were isolated, and it was
found that the product yielded 1,2-epoxydihydronaphthalene as well as
naphthalene.
Introduction
In 1990, professor E.N. Jacobsen reported that chiral manganese
complexes had the ability to catalyze the asymmetric epoxidation of
unfunctionalized alkenes, providing enantiomeric excesses that regularly
reaching 90% and sometimes exceeding 98% . The chiral manganese complex
Jacobsen utilized was [(R,R)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-
cyclohexanediaminato-(2-)]-manganese (III) chloride (Jacobsen's Catalyst)...
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