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Consider a specimen of fine particles having no preferred orientation of its particles. If we have spherical particles, there will be no shape anisotropy, and the same applied field will magnetize it to the same extent in any direction. But if it is a nonspherical particles, the magnetization vector will not necessarily lie along an easy crystallographic axis, but rather along an axis whose demagnetizating field is a minimum. This is called shape anisotropy and was proposed by (1947).
In real systems, there is always a particle size and shape distributions as well as a distribution of particle environments
, depending on the topology of the system (e...
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