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Thin enough that we are capable enough to change its composition.
Over the past two hundred years the burning of fossil fuels such as, coal and oil, and deforestation have caused the concentrations of green house gases to increase. Which in turn causes the atmosphere to thicken. This prevents heat from escaping the earth for example like panels in a green house.
The suns radiation comes to earth in the form of light waves. Most of this is absorbed by the earth and heats it. The earth sends some of this energy back to space in the form of infrared waves. Again some of this is trapped by the earth...
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