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They only contain carbon-hydrogen bonds and carbon-carbon single bonds. The first six are:
methane CH4
ethane C2H6
propane C3H8
butane C4H10
pentane C5H12
hexane C6H14
You can work out the formula of any of them using: CnH2n+2
Isomerism
All the alkanes with 4 or more carbon atoms in them show structural isomerism. This means that there are two or more different structural formulae that you can draw for each molecular formula.
For example, C4H10 could be either of these two different molecules:
These are called respectively butane and 2-methylpropane.
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Note: If you aren't confident about naming organic compounds, the various ways of drawing organic compounds, or structural isomerism, then you really ought to follow these links before you go on...
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